The Ohio State UniversityDepartment of Chemistry
The Rajanbabu Research Group

[fancybullet.png] Original Publications
[fancybullet.png] Reviews - Periodicals and Book Chapters
[fancybullet.png] US Patents

Publications by Topic

- Organosilicon Chemistry
+ Novel Cyclizations
+ Free Radical Chemistry
- Low-valent Zr/Ti Chemistry
+ Asymmetric Catalysis
+ Design and Application of New Ligands
+ Miscellaneous

Original Publications - All
Number
Title, Authors
 Journal, Year, Volume, Pages

105
"Coupling of Propylene Oxide and Lactide at a Porphyrin Chromium(III) Center", Balasanthiran, V.; Chatterjee, C.; Chisholm, M. H.; Harrold, N. D.; RajanBabu, T. V.; Warren, G. A.
 J. Am. Chem. Soc. 2015, 137, 1786-1789.


104
"Chemoselective Reactions of (E)-1,3-Dienes: Cobalt-Mediated Isomerization to (Z)-1,3-Dienes and Reactions with Ethylene", Timsina, Y. T.; Biswas, S.; RajanBabu, T. V.
 J. Am. Chem. Soc. 2014, 136, 6215-6218.


103
"Triarylphosphine Ligands with Hemilabile Alkoxy Groups. Ligands for Nickel(II)-Catalyzed Olefin Dimerization Reactions. Hydrovinylation of Vinylarenes, 1,3-Dienes, and Cycloisomerization of 1,6-Dienes", Biswas, S.; Zhang, A.; Raya, B.; RajanBabu, T. V.
 Adv. Synth. Catal. 2014, , (In Press)


102
"Bimetallic Catalysis in the Highly Stereoselective Ring-Opening Reactions of Aziridines", Wu, B.; Gallucci, J. C.; Parquette, J. R.; RajanBabu, T. V.
 Chem. Sci. 2014, 5, 1102-1117.


101
"Highly Efficient Catalytic Dimerization of Styrenes via Cationic Palladium(II) Complexes", Choi, J. H.; Kwon, J. K.; RajanBabu, T. V.; Lim, H. J.
 Adv. Synth. Catal. 2013, 355, 3633-3638.


100
"Conformation and reactivity in dibenzocyclooctadienes (DBCOD). A general approach to the total synthesis of fully substituted DBCOD lignans via borostannylative cyclization of ?,?-diynes", Gong, W.; RajanBabu, T. V.
 Chem. Sci. 2013, 4, 3979-3985.


99
"Asymmetric Hydrovinylation of 1-Vinylcycloalkenes. Reagent Control of Regio- and Stereoselectivity", Page, J. P.; RajanBabu, T. V.
 J. Am. Chem. Soc. 2012, 134, 6556-6559.Download PDF Document


98
"Asymmetric Hydrovinylation of Vinylindoles. A Facile Route to Cyclopenta[g]indole Natural Products (+)-cis-Trikentrin A and (+)-cis-Trikentrin B", Liu, W.; Lim, H. J.; RajanBabu, T. V.
 J. Am. Chem. Soc. 2012, 134, 5496-5499.Download PDF Document


97
"On the stereochemistry of acetylide additions to highly functionalized biphenylcarbaldehydes and multi-component cyclization of 1,n-diynes. syntheses of dibenzocyclooctadiene lignans.", Gong, W.; Singidi, R. R.; Gallucci, J. C.; RajanBabu, T. V.
 Chem. Sci. 2012, 3, 1221-1230.Download PDF Document


96
"Ethylene in Organic Synthesis: A New Route to Anticholenergic Pyrrolidinoindolines, and Other Molecules with All Carbon-Quaternary Centers via Asymmetric Hydrovinylation", Lim, H. J.; RajanBabu, T. V.
 Org. Lett. 2011, 13, 6596-6599.Download PDF Document


95
"Ethylene in Organic Synthesis. Repetitive Hydrovinylation of Alkenes for Highly Enantioselective Syntheses of Pseudopterosins", Mans, D. J.; Cox, G. A.; RajanBabu, T. V.
 J. Am. Chem. Soc. 2011, 133, 5776-5779.Download PDF Document


94
"Reactivity and Selectivity in Hydrovinylation of Strained Alkenes", Liu, W.; RajanBabu, T. V.
 J. Org. Chem. 2010, 75, 7636-7643.Download PDF Document


93
"Stereoselective Cyclization of Functionalized 1,n-Diynes Mediated by [X-Y]- Reagents [X-Y = R3Si-SnR'3 or (R2N)2B-SnR'3]. Synthesis and Properties of Atropisomeric 1,3-Dienes", Singidi, R. R.; Kutney, A. M.; Gallucci, J. C.; RajanBabu, T. V.
 J. Am. Chem. Soc. 2010, 132, 13078-13087.Download PDF Document


92
"Borostannylation of Alkynes and Enynes. Scope and Limitations of the Reaction and Utility of the Adducts", Singidi, R. R.; RajanBabu, T. V.
 Org. Lett. 2010, 12, 2622-2625.Download PDF Document


91
"Annulated Diketopiperazines from Dipeptides or Schollkopf Reagents via Tandem Cyclization-N-Arylation", Lim, H. J.; Gallucci, J. C.; RajanBabu, T. V.
 Org. Lett. 2010, 12, 2162-2165.Download PDF Document


90
"Mechanism and Stereoselection in a Y-Catalyzed Transacylation Reaction. A Computational Modeling Study", Sanan, T.T; RajanBabu, T. V.; Hadad, C. M.
 J. Org. Chem. 2010, 75, 2369-2381.Download PDF Document


89
"Asymmetric Hydrovinylation of Unactivated Linear 1,3-Dienes", Sharma, R. S.; RajanBabu, T. V.
 J. Am. Chem. Soc. 2010, 132, 3295-3297.Download PDF Document


88
"A Low Pressure Vinylation of Aryl and Vinyl Halides via Mizoroki-Heck Reactions Using Ethylene", Smith, C. R.; RajanBabu, T. V.
 Tetrahedron 2010, 66, 1102-1110.Download PDF Document


87
"Regiodivergent Ring Opening of Chiral Aziridines", Wu, B.; Parquette, J. R.; RajanBabu, T. V.
 Science 2009, 326, 1662.Download PDF Document


86
"Seleniranium Ion-Triggered Reactions:New Aspects of Friedel-Crafts and N-Detosylative Cyclizations", Lim, H. J.; RajanBabu, T. V.
 Org. Lett. 2009, 11, 2924-2927.Download PDF Document


85
"Tunable Phosphoramidite Ligands for Asymmetric Hydrovinylation: Ligands par excellence for Generation of All-Carbon Quaternary Centers", Smith, C. R.; Lim, H. J.; Zhang, A.; RajanBabu, T. V.
 Synthesis 2009, 12, 2089-2100.Download PDF Document


84
"Catalytic Asymmetric Synthesis Using Feedstocks. An Enantioselective Route to 2-Arylpropionic Acids and 2-Arylethyl Amines via Hydrovinylation of Vinylarenes", Smith, C. R.; RajanBabu, T. V.
 J. Org. Chem. 2009, 74, 3066-3072.Download PDF Document


83
"Facile Pd(II)- and Ni(II)-Catalyzed Isomerization of Terminal Alkenes", Lim, H. J.; Smith, C. R.; RajanBabu, T. V.
 J. Org. Chem. 2009, 74, 4565-4572.Download PDF Document


82
"A Theoretical Investigation of the Mechanism of Hydrovinylation Reaction", Joseph, J.; RajanBabu, T. V.; Jemmis, E. D.
 Organometallics 2009, 28, 3552-3566.Download PDF Document


81
"Enantioselective Desymmetrization of meso-Aziridines by TMSN3 and TMSCN Catalyzed by Discrete Yttrium Complexes", Wu, B.; Gallucci, J. C.; Parquette, J. R.; RajanBabu, T. V.
 Angew. Chem. Int. Ed. 2009, 48, 1126-1129.Download PDF Document


80
"In Pursuit of an Ideal Carbon-Carbon Bond-Forming Reaction. The Hydrovinylation of Alkenes", RajanBabu, T. V.; Nomura, N.; Jin, J.; Nandi, M.; Park, H.; Ramaiah, K.; Zhang, A.; Saha, B.; Mans, D.; Smith, C. R.; Lim, H.
 Synlett 2009, 21, 853-885.Download PDF Document


79
"Catalyzed Cyclizations Leading to Enrichment of Functionality and Chirality. A General Approach to Dibenzocyclooctadiene Lignans from α,ω-Diynes", Singidi, R. R.; RajanBabu, T. V
 Org. Lett. 2008, 10, 3351-3354.Download PDF Document


78
"Conformationally Driven Asymmetric Induction in a Catalytic Dendrimer", Yu, J.; RajanBabu, T. V.; Parquette, J. R.
 J. Am. Chem. Soc. 2008, 130, 7845-7847.Download PDF Document


77
"Efficient, Selective and Green: Catalyst Tuning for Highly Enantioselective Reactions of Ethylene", Smith, C. R.; RajanBabu, T. V.
 Org. Lett. 2008, 10, 1657-1659.Download PDF Document


76
"Ligand Tuning in Asymmetric Hydrovinylation of 1,3-Dienes. A Stereoselective Route to either Steroid-C20(S) or -C20(R) Derivatives", Saha, B.; Smith, C. R.; RajanBabu, T. V.
 J. Am. Chem. Soc. 2008, 130, 9000-9005.Download PDF Document


75
"(R)-3-Methyl-3-phenyl-1-pentene via Catalytic Asymmetric Hydrovinylation", Smith, C. R.; Zhang, A.; Mans, D.; RajanBabu, T. V.
 Org. Synth. 2008, 85, 238-247.Download PDF Document


74
"(R)-2,2-Binaphthoyl-(S,S)-Di(1-phenylethyl) Aminophosphine. Scalable Protocols for the Synthesis of Phosphoramidite (Feringa) Ligands", Smith, C. R.; Mans, D.; RajanBabu, T. V.
 Org. Synth. 2008, 85, 248-266.Download PDF Document


73
"Exceptionally Active Yttrium-Salen Complexes for the Catalyzed Ring Opening of Epoxides by TMSCN and TMSN3", Saha, B.; Lin, M- H.; RajanBabu, T. V.
 J. Org. Chem. 2007, 72, 8648-8655.Download PDF Document


72
"Syntheses and Applications of 2-Phosphino-2'-alkoxy-1,1'-binaphthyl Ligands. Development of a Working Model for Asymmetric Induction in Hydrovinylation Reactions", Saha, B.; RajanBabu, T. V.
 J. Org. Chem. 2007, 72, 2357-2363.Download PDF Document


71
"Nickel(0)-Catalyzed Asymmetric Hydrocyanation of 1,3-Dienes", Saha, B.; RajanBabu, T. V.
 Org. Lett. 2006, 8, 4657-4659.Download PDF Document


70
"All Carbon Quaternary Centers via Asymmetric Hydrovinylation. New Approaches to the Exocyclic Side Chain Stereochemistry Problem", Zhang, A.; RajanBabu, T. V.
 J. Am. Chem. Soc. 2006, 128, 5620-5621.Download PDF Document


69
"Hydrovinylation of 1,3-Dienes: A New Protocol, an Asymmetric Variation, and a Potential Solution to the Exocyclic Side Chain Stereochemistry Problem", Zhang, A.; RajanBabu, T. V.
 J. Am. Chem. Soc. 2006, 128, 54-55.Download PDF Document


68
"Tunable Phosphinite, Phosphite and Phosphoramidite Ligands for Asymmetric Hydrovinylation Reaction", Park, H.; Kumareswaran, R.; RajanBabu, T. V.
 Tetrahedron 2005, 61, 6352-6367.Download PDF Document


67
"Silylstannylation of Highly Functionalized Acetylenes. Synthesis of Precursors for Annulations via Radical or Heck Reactions", Apte, S.; Radetich, B.; Shin, S.; RajanBabu, T. V.
 Org. Lett. 2004, 6(22), 4053-4056.Download PDF Document


66
"Tuning the Acceptors in Catalyzed Cyclizations Initiated by Allenes. Silylstannylation/Cyclization of Allene-Aldehydes for Synthesis of Indolizidine including 223A Congeners", Kumareswaran, R.; Gallucci, J.; RajanBabu, T. V.
 J. Org. Chem. 2004, 69(26), 9151-9158.Download PDF Document


65
"Chiral Benzyl Centers through Asymmetric Catalysis. A Three Step Synthesis of (R)-(-)- α-Curcumene", Zhang, A.; RajanBabu, T. V.
 Org. Lett. 2004, 6, 3159-3162.Download PDF Document


64
"Silylstannylation of Allenes and Silylstannylation-Cyclization of Allenynes. Synthesis of Highly Functionalized Allyl Stannanes, Carbocyclic and Heterocyclic Compounds", Kumareswaran, R.; Shin, S.; Gallou, I.; RajanBabu, T. V.
 J. Org. Chem. 2004, 69, 7157-7170.Download PDF Document


63
"Homogeneous Two-Component Polycondensation without Strict Stoichiometric Balance via the Tsuji-Trost Reaction: Remote Control of Two Reaction Sites by Catalysis", Nomura, N.; Tsurugi, K.; RajanBabu, T. V. Kondo, T.
 J. Am. Chem. Soc. 2004, 126, 5354-5355.Download PDF Document


62
"Fine-tuning Monophosphine Ligands for Enhanced Enantioselectivity. Influence of Chiral Hemilabile Pendant Groups", Zhang, A.; RajanBabu, T. V.
 Org. Lett. 2004, 6(9), 1515-1517.Download PDF Document


61
"Heterodimerization of Olefins 1. Hydrovinylation Reactions of Olefins That Are Amenable to Asymmetric Catalysis", RajanBabu, T. V.; Nomura, N.; Jin, J.; Nandi, M.; Park, H.; Sun, X.
 J. Org. Chem. 2003, 68, 8431-8446.Download PDF Document


60
"Hydrovinylation of Norbornene. Ligand Dependent Selectivity and Asymmetric Variations", Kumareswaran, R.; Nandi, N.; RajanBabu, T. V.
 Org. Lett. 2003, 5, 4345-4348.Download PDF Document


59
"Axial Chirality in 1,4-Disubstituted (ZZ)-1,3-Dienes. Surprisingly Low Activation Barriers for Enantiomerization in Synthetically Useful Fluxional Molecules", Warren, S.; Chow, A.; Fraenkel, G.; RajanBabu, T. V.
 J. Am. Chem. Soc. 2003, 125, 15402-15410.Download PDF Document


58
"Stereochemical Control in Radical Cyclization Routes to N-Glycosides: Role of Protecting Groups and of the Configuration (E vs. Z) of the Acceptors", Rhee, J. U.; Bliss, B. I.; RajanBabu, T. V.
 Tetrahedron Asymmetry 2003, 14(19), 2939-2959.Download PDF Document


57
"Asymmetric Hydrovinylation Reaction", RajanBabu, T. V.
 Chem. Rev. 2003, 103(8), 2845-2860.Download PDF Document


56
"A New Reaction Manifold for the Barton Radical Intermediates. Synthesis of N-Heterocyclic Furanosides and Pyranosides through the Formation of the C1-C2 Bond", Rhee, J. U.; Bliss, B. I.; RajanBabu, T. V.
 J. Am. Chem. Soc. 2003, 125, 1492-1493.Download PDF Document


55
"Ligand-assisted Rate Acceleration in Transacylation by a Yttrium-Salen Complex. Demonstration of a Conceptually New Strategy for Metal-catalyzed Kinetic Resolution of Alcohols", Lin, M. H.; RajanBabu, T. V.
 Org. Lett. 2002, 4, 1607-1610.Download PDF Document


54
"Tunable Ligands for Asymmetric Catalysis. Readily Available Carbohydrate-derived Diarylphosphinites Induce High Selectivity in the Hydrovinylation of Styrene Derivatives", Park, H.; RajanBabu,T. V.
 J. Am. Chem. Soc. 2002, 124, 734-735.Download PDF Document


53
"Synthesis, Characterization and Applicability of Neutral, Polyhydroxy Phospholane Derivatives and Their Rhodium (I) Complexes for Reactions in Organic and Aqueous Media", RajanBabu, T. V.; Yan, Y.; Shin, S.
 J. Am. Chem. Soc. 2001, 123, 10207-10212.Download PDF Document


52
"Regio- and Stereochemical Control in Bis-functionalization-Cyclization. Use of Alleneyne Precusors for Carbocyclic and Heterocyclic Synthesis", Shin, S.; RajanBabu, T. V.
 J. Am. Chem. Soc. 2001, 123, 8416-8417.Download PDF Document


51
"Asymmetric Synthesis of Functionalized 1,2,3,4-Tetrahydroquinolines", Gallou-Dagommer, I.; Gastaud, P.; RajanBabu, T. V.
 Org. Lett. 2001, 3, 2053-2056.Download PDF Document


50
"Water-Soluble Organometallic Catalysts from Carbohydrates. 2. A Strategy for the Preparation of Catalysts with Pendant Quaternary Ammonium Groups Using D-Salicin", Yan, Y.-Y.; RajanBabu, T. V.
 J. Org. Chem. 2001, 66, 3277-3283.Download PDF Document


49
"First Demonstration of Helical Chirality in 1,4-Disubstituted (Z,Z)-1,3-Dienes. R3Si-SnR'3-mediated Cyclization of 1,6-Diynes", Gréau, S.; Radetich, B.; RajanBabu, T. V.
 J. Am. Chem. Soc. 2000, 122, 8579-8580.Download PDF Document


48
"Ligand Substituent Effects on Asymmetric Induction. Effect of Structural Variations of the DIOP Ligand on the Rh-Catalyzed Asymmetric Hydrogenation of Enamides", Yan, Y.; RajanBabu, T. V.
 Org. Lett. 2000, 2, 4137-4140.Download PDF Document


47
"Ligand Tuning in Asymmetric Catalysis: Mono- and Bis-Phospholanes for a Prototypical Pd-Catalyzed Asymmetric Allylation Reaction", Yan, Y.-Y.; RajanBabu, T. V.
 Org. Lett. 2000, 2, 199-202.Download PDF Document


46
"Heterodimerization of Propylene and Vinylarenes: Functional Group Compatibility in a Highly Efficient Ni-Catalyzed Carbon-Carbon Bond-Forming Reaction", Jin, J.; RajanBabu, T. V.
 Tetrahedron 2000, 56, 2145-2151.Download PDF Document


45
"Highly Flexible Synthetic Routes to Functionalized Phospholanes from Carbohydrates", Yan, Y.; RajanBabu, T. V.
 J. Org. Chem. 2000, 65, 900-906.Download PDF Document


44
"Metal-Catalyzed Acyl Transfer Reactions of Enol Esters: Role of Y5(OiPr)13O as a Superb Transesterification Catalyst", Lin. M. -H.; RajanBabu, T. V.
 Org. Lett. 2000, 2, 997-1000.Download PDF Document


43
"First Chelated Chiral N-Heterocyclic bis-Carbene Complexes", Clyne, D. S.; Jin, J.; Genest, Gallucci, J. C.; RajanBabu, T. V.
 Org. Lett. 2000, 2, 1125-1128.Download PDF Document


42
"Water-Soluble Organometallic Catalysts from Carbohydrates. 1. Diarylphosphinite-Rh Complexes", Shin, S.; RajanBabu, T. V.
 Org. Lett. 1999, 1, 1229-1232.Download PDF Document


41
"Synergistic Effects of Hemilabile Coordination and Counterions in Homogeneous Catalysis: New Tunable Monophosphine Ligands for Hydrovinylation Reactions", Nandi, M.; Jin, J.; RajanBabu, T. V.
 J. Am. Chem. Soc. 1999, 121, 9899-9900.Download PDF Document


40
"Substituent Effects of Ligands on Asymmetric Induction in a Prototypical Palladium-Catalyzed Allylation Reaction: Making Both Enantiomers of a Product in High Optical Purity Using the Same Source of Chirality", Clyne, D. S.; Mermet-Bouvier, Y. C.; Nomura, N.; RajanBabu, T. V.
 J. Org. Chem. 1999, 64, 7601-7611.Download PDF Document


39
"Hydrovinylation and Related Reactions: New Protocols and Control Elements in Search of Greater Synthetic Efficiency and Selectivity", RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M.
 Chem. Eu. J. 1999, 5, 1963-1968.Download PDF Document


38
"Electronic Effects in Asymmetric Catalysis: Structural Studies of Precatalysts and Intermediates in Rh-Catalyzed Hydrogenation of Dimethyl Itaconate and Acetamidocinnamic Acid Derivatives Using C2-Symmetric Diarylphosphinite Ligands", RajanBabu, T. V.; Radetich, B.; You, K. K.; Ayers, T. A.; Casalnuovo, A. L.; Calabrese, J. C.
 J. Org. Chem. 1999, 64, 3429-3447.Download PDF Document


37
"Catalytic Cyclization of α,ω-Dienes: A Versatile Protocol for the Synthesis of Functionalized Carbocylic and Heterocyclic Compounds", Radetich, B.; RajanBabu, T. V.
 J. Am. Chem. Soc. 1998, 120, 8007-8008.Download PDF Document


36
"The Hydrovinylation Reaction: A New Highly Selective Protocol Amenable to Asymmetric Catalysis", Nomura, N.; Jin, J.; Park, H.; RajanBabu, T. V.
 J. Am. Chem. Soc. 1998, 120, 459-460.Download PDF Document


35
"Carbohydrate Phosphinites as Practical Ligands in Asymmetric Catalysis: Electronic Effects and Dependence of Back-bone Chirality in Rh-Catalyzed Asymmetric Hydrogenations. Synthesis of R- or S- Amino Acids Using Natural Sugars as Ligand Precursors", RajanBabu, T. V.; Ayers, T. A.; Halliday, G. A.; You, K. K.; Calabrese, J. C.
 J. Org. Chem. 1997, 62, 6012-6028.Download PDF Document


34
"Nickel-Catalyzed Asymmetric Allylation of Alkyl Grignard Reagents. Effect of Ligands, Leaving Groups and a Kinetic Resolution with a Hard Nucleophile", Nomura, N.; RajanBabu, T. V.
 Tetrahedron Lett. 1997, 38, 1713-1716.Download PDF Document


33
"Role of Electronic Asymmetry in the Design of New Ligands: The Asymmetric Hydrocyanation Reaction", RajanBabu, T. V.; Casalnuovo, A. L.
 J. Am. Chem. Soc. 1996, 118, 6325-6326.Download PDF Document


32
"Unprecedented Electronic and Steric Effects in Palladium-Catalyzed Asymmetric Allylation: Switching of Enantioselectivity with a Single Chiral Back-bone", Nomura, N.; Mermet-Bouvier, Y. C.; RajanBabu, T. V.
 Synlett. 1996, 8, 745-746.Download PDF Document


31
"Ligand Electronic Effects in Asymmetric Catalysis: Enhanced Enantioselectivity in Asymmetric Hydrocyanation of Vinylarenes", Casalnuovo, A. L.; RajanBabu, T. V.; Ayers, T. A.; Warren, T.
 J. Am. Chem. Soc. 1994, 116, 9869-9882.Download PDF Document


30
"Electronic Effects in Asymmetric Catalysis: Hydroformylation of Olefins", RajanBabu, T. V.; Ayers, T. A.
 Tetrahedron Lett. 1994, 35, 4295-4298.Download PDF Document


29
"Electronic Amplification of Selectivity in Rh-Catalyzed Hydrogenations: D-Glucose-Derived Ligands for the Synthesis of D- or L- Amino Acids", RajanBabu, T. V.; Ayers, T. A.; Casalnuovo, A. L.
 J. Am. Chem. Soc. 1994, 116, 4101-4102.Download PDF Document


28
"Selective Generation of Free Radicals from Epoxides Using a Transition-Metal Radical. A Powerful New Tool for Organic Synthesis", RajanBabu, T. V.; Nugent, W. A.
 J. Am. Chem. Soc. 1994, 116, 986-997.Download PDF Document


27
"Beyond Nature's Chiral Pool: Enantioselective Catalysis in Industry", Nugent, W. A.; RajanBabu, T. V.; Burk, M. J.
 Science 1993, 259, 479-483.Download PDF Document


26
"Tailored Ligands For Asymmetric Catalysis", RajanBabu, T. V.; Casalnuovo, A. L.
 J. Am. Chem. Soc. 1992, 114, 6265-6266.Download PDF Document


25
"Stereochemistry of Intramolecular Free-Radical Cyclization Reactions", RajanBabu, T. V.
 Acc. Chem. Res. 1991, 24, 139-145.Download PDF Document


24
"Free Radical Mediated Reduction and Deoxygenation of Epoxides", RajanBabu, T. V.; Nugent, W. A.; Beattie, M. S.,
 J. Am. Chem. Soc. 1990, 112, 6408-6409.Download PDF Document


23
"Intermolecular Addition of Epoxides to Activated Olefines: A New Reaction", RajanBabu, T. V.; Nugent, W. A.
 J. Am. Chem. Soc. 1989, 111, 4525-4527.Download PDF Document


22
"Conformational Effects on Hex-5-enyl Radical Cyclizations: From Carbohydrates to Carbocycles III", RajanBabu, T. V.; Fukunaga, T.; Reddy, G. S.
 J. Am. Chem. Soc. 1989, 111, 1759-1769.Download PDF Document


21
"Stereochemical Control in Hex-5-enyl Radical Cyclizations: Axial vs. Equatorial 2-(But-3-enyl)cyclohexyl Radicals", RajanBabu, T. V.; Fukunaga, T.
 J. Am. Chem. Soc. 1989, 111, 296.Download PDF Document


20
"Transition Metal-Centered Radicals in Organic Synthesis - Ti(III)-Induced Cyclization of Epoxyolefins", Nugent, W. A.; RajanBabu T. V.
 J. Am. Chem. Soc. 1988, 110, 8561-8562.Download PDF Document


19
"Stereoselective Cyclization of Enynes Mediated by Metallocene Reagents", RajanBabu, T. V.; Nugent, W. A.; Taber, D. F.; Fagan, P. J.
 J. Am. Chem. Soc. 1988, 110, 7128-7135.Download PDF Document


18
"Group Transfer Polymerization With Polyunsaturated Esters and Silylpolyenolates", Hertler, W. R.; RajanBabu T. V.: Sogah, D. Y.: Ferguson, R. C.: Ovenall, D. W.: III, Reddy, G. S.
 J. Am. Chem. Soc. 1988, 110, 5841-5853.Download PDF Document


17
"From Carbohydrates to Optically Active Carbocycles, II: A Free Radical Route to Corey-Lactone From 3-Deoxyglucose", RajanBabu, T. V.
 J. Org. Chem. 1988, 53, 4522-4530.Download PDF Document


16
"From Carbohydrates to Optically Active Carbocycles, I: Stereochemical Control in Sugar Hex-5-enyl Radical Cyclization", RajanBabu T. V.
 J. Am. Chem. Soc. 1987, 109, 609-610.Download PDF Document


15
"1-Methylene Sugars as C-Glycoside Precursors", RajanBabu, T. V.; Reddy, G. S.
 J. Org. Chem. 1986, 51, 5458.Download PDF Document


14
"α-Nitroarylation of Ketones and Esters: An Exceptionally Facile Synthesis of Indoles, 2-Indolinones and Arylacetic Acids", RajanBabu, T. V.; Chenard, B. L.; Petti, M. A.
 J. Org. Chem. 1986, 51, 1704-1712.Download PDF Document


13
"Silylstannanes: Useful Reagents for Bis-Functionalization of α,β-Unsaturated Ketones and Acetylenes", Chenard, B. L.; Laganis, E. D.; Davidson, F.; RajanBabu, T. V.,
 J. Org. Chem. 1985, 50, 3666.Download PDF Document


12
"Pd(0)-Catalyzed C-Glycosylation: A Facile Alkylation of Trifluoroacetylglucal", RajanBabu, T. V.
 J. Org. Chem. 1985, 50, 3642-3644.Download PDF Document


11
"Nucleophilic Addition of Silyl Enol Ethers to Aromatic Nitrocompounds: Scope and Mechanism of Reaction", RajanBabu T. V.; Reddy, G. S.; Fukunaga, T.
 J. Am. Chem. Soc. 1985, 107, 5473-5483.Download PDF Document


10
"Nucleophilic Addition of Silyl Enol Ethers to Aromatic Nitrocompounds: A Facile Synthesis of α-Nitroaryl Carbonyl Compounds", RajanBabu, T. V.; Fukunaga, T.
 J. Org. Chem. 1984, 49, 4571-4572.Download PDF Document


9
"Addition of Ketene Trimethylsilyl Acetals to α,β-Unsaturated Ketones: A New Strategy for Michael Addition of Ester Enolates", RajanBabu T. V.
 J. Org. Chem. 1984, 49, 2083-2089.Download PDF Document


8
"Synthesis of Reactive-Ended Acrylic Polymers by Group Transfer Polymerization: Initiation with Silyl Ketene Acetals", Webster, O. W.; Hertler, W. R.; Sogah, D. Y.; Farnham, W. B.; RajanBabu T. V.
 J. Macromol. Sci.-Chem. 1984, A21 (8&9), 943-960.Download PDF Document


7
"Group Transfer Polymerization, 1. A New Concept for Addition Polymerization with Organosilicon Initiators", Webster, O. W.; Hertler, W. R.; Sogah, D. Y.; Farnham, W. B.; RajanBabu T. V.
 J. Am. Chem. Soc. 1983, 105, 5706-5707.Download PDF Document


6
"Chemistry of Bridged Aromatics. A Study of the Substituent Effect on the Course of Bond Cleavage of 9,10-Dihydro-9,10-ethanoanthracenes and an Oxyanion-Assisted Retro-Diels-Alder Reaction", RajanBabu, T. V.; Eaton, D. F.; Fukunaga, T.
 J. Org. Chem. 1983, 48, 652-657.Download PDF Document


5
"Asymmetric Total Synthesis of Erythromycin, 1. Synthesis of an Erythronolide A Seco Acid Derivative via Asymmetric Induction", Woodward, R. B.; ... RajanBabu, T. V. et al, (41 Authors)
 J. Am. Chem. Soc. 1981, 103, 3210-3213.Download PDF Document


4
"Asymmetric Total Synthesis of Erythromycin, 2. Synthesis of an Erythronolide A Lactone System", Woodward, R. B.; ... RajanBabu, T. V. et al, (41 Authors)
 J. Am. Chem. Soc. 1981, 103, 3213-3215.Download PDF Document


3
"Asymmetric Total Synthesis of Erythromycin, 3. Total Synthesis of Erythromycin", Woodward, R. B.; ... RajanBabu, T. V. et al, (41 Authors)
 J. Am. Chem. Soc. 1981, 103, 3215-3217.Download PDF Document


2
"Surprises in Base-Catalyzed Decompositions of Bicyclo[4.2.1]nona-2,4,7-trien-9-one Hydrazone", RajanBabu T. V.; Sanders, D. C.; Shechter, H.
 J. Am. Chem. Soc. 1977, 99, 6449-6450.Download PDF Document


1
"Carbenic Rearrangement and Fragmentation of Bicyclo[4.2.2]-deca-2,4,9-trien-7-ylidene and Bicyclo[4.2.1]nona-2,4,7-trien-9-ylidene", RajanBabu, T. V.; Shechter, H.
 J. Am. Chem. Soc. 1976, 98, 8261-8262.Download PDF Document

Contact Information
T. V. (Babu) RajanBabu
Department of Chemistry
The Ohio State University
100 West 18th Avenue
Columbus, Ohio 43210

Tel. (614) 688-3543
Fax (614) 292-1685
babu@chemistry.ohio-state.edu

Postdoctoral Positions
Only applications sent by regular mail will be considered. Please include full CV, research accomplishments, career objectives, and list of references.
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